Department of Chemistry

Dominic S Wright Publications


2014


A Study of the Optical Properties of Metal-doped Polyoxotitanium Cages and the Relationship to Metal-doped Titania
YaoKang Lv, Jun Cheng, Peter Matthews, Juan P Holgado, Janina Willkomm, Michal Leskes, Alexander Steiner, Dieter Fenske, Timothy C King, Paul Wood, Lihua Gan, Richard M Lambert, Dominic S Wright
Dalton_Transactions DOI: 10.1039/C4DT00555D


Reactivity and catalytic activity of tert-butoxy-aluminium hydride reagents.
Less RJ, Simmonds HR, Wright DS
Dalton Trans, 2014, -. DOI: 10.1039/C4DT00152D


Direct access to [(Mes*P)2As](-), a 1,3-diphosphaarsa-2-allyl anion, isoelectronic with the allyl anion (Mes* = 2,4,6-(t)Bu3C6H2).
Dixon LS, Allen LK, Less RJ, Wright DS
Chem Commun (Camb), 2014, 23, 3007-3009. DOI: 10.1039/C3CC49627A


Dipole-induced band-gap reduction in an inorganic cage.
Lv Y, Cheng J, Steiner A, Gan L, Wright DS
Angew Chem Int Ed Engl, 2014, 7, 1934-1938. DOI: 10.1002/anie.201307721


Dehydrocoupling of amine boranes via tin(IV) and tin(II) catalysts
Erickson KA, Wright DS, Waterman R
Journal of Organometallic Chemistry, 2014, 541-545.

2013


Base-Induced 1,3-Sigmatropic Rearrangement of Mesitylphosphonium Salts
Sophia A Solomon, Lucy K Allen, Sarah B J Dane and Dominic S Wright
European_Journal_of_Inorganic_Chemistry DOI: 10.1002/ejic.201301203


Chiral Ditopic Cyclophosphazane (CycloP) Ligands: Synthesis, Coordination Chemistry, and Application in Asymmetric Catalysis
Dipl.-Chem Torsten Roth, Prof. Dr Hubert Wadepohl, Prof. Dr Dominic S Wright and Prof. Dr Lutz H Gade
Chemistry_-_A_European_Journal DOI: 10.1002/chem.201302327


Yi-Hsuan Lai, Timothy C King, Prof Dominic S Wright and Dr Erwin Reisner
Chemistry_-_A_European_Journal DOI: 10.1002/chem.201302641


Reactions of Cp2M (M = Ni, V) with dilithium diamido-aryl reagents; retention and oxidation of the transition metal ions.
Stokes FA, Vincent MA, Hillier IH, Ronson TK, Steiner A, Wheatley AE, Wood PT, Wright DS
Dalton Trans, 2013, 38, 13923-13930. DOI: 10.1039/C3DT51632F


A Seeded Synthetic Strategy to Uniform Polymer and Carbon Nanospheres with Tunable Sizes for High Performance Electrochemical Energy Storage
Jiasheng Qian, Mingxian Liu, LiHua Gan, Pranav Kumar Tripathi, Dazhang Zhu, Zijie Xu, Zhixian Hao, Longwu Chen, Dominic S Wright
Chemical_Communications DOI: 10.1039/C3CC41113C


Stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3.
Less RJ, Simmonds HR, Dane SB, Wright DS
Dalton Trans, 2013, 18, 6337-6343. DOI: 10.1039/C2DT32569A


Solvent Direction of Molecular Architectures in Group 1 Metal Pentacyanocyclopentadienides
Robert J Less, Thomas C Wilson, Bihan Guan, Mary McPartlin, Alexander Steiner, Paul T Wood and Dominic S Wright
European_Journal_of_Inorganic_Chemistry DOI: 10.1002/ejic.201201342


Solvent direction of molecular architectures in group 1 metal pentacyanocyclopentadienides
Less RJ, Wilson TC, Guan B, McPartlin M, Steiner A, Wood PT, Wright DS
European Journal of Inorganic Chemistry, 2013, 7, 1161-1169.


Dehydrocoupling of amine boranes via tin(IV) and tin(II) catalysts
Erickson KA, Wright DS, Waterman R
Journal of Organometallic Chemistry, 2013, -.


Chiral ditopic cyclophosphazane (CycloP) ligands: Synthesis, coordination chemistry, and application in asymmetric catalysis
Roth T, Wadepohl H, Wright DS, Gade LH
Chemistry - A European Journal, 2013, 41, 13823-13837.


A seeded synthetic strategy for uniform polymer and carbon nanospheres with tunable sizes for high performance electrochemical energy storage
Qian J, Liu M, Gan L, Tripathi PK, Zhu D, Xu Z, Hao Z, Chen L, Wright DS
Chemical Communications, 2013, 29, 3043-3045.


A low-temperature single-source route to an efficient broad-band cerium(iii) photocatalyst using a bimetallic polyoxotitanium cage
Lv Y, Yao M, Holgado JP, Roth T, Steiner A, Gan L, Lambert RM, Wright DS
RSC Advances, 2013, 33, 13659-13662.


Scalable one-step assembly of an inexpensive photoelectrode for water oxidation by deposition of a Ti- and Ni-containing molecular precursor on nanostructured WO3
Lai Y-H, King TC, Wright DS, Reisner E
Chemistry - A European Journal, 2013, 39, 12943-12947.


A single-source route to bulk samples of C3N and the co-evolution of graphitic carbon microspheres
King TC, Matthews PD, Holgado JP, Jefferson DA, Lambert RM, Alavi A, Wright DS
Carbon, 2013, 6-10.

2012


The redox effect of the [1,2-(NH)2C6H4]2- ligand in the formation of transition metal compounds.
Stokes FA, Kloo L, Lv Y, Harford PJ, Wheatley AE, Wright DS
Chem Commun (Camb), 2012, 92, 11298-11300. DOI: 10.1039/C2CC35213C


Facile assembly of an efficient CoO(x) water oxidation electrocatalyst from Co-containing polyoxotitanate nanocages.
Lai YH, Lin CY, Lv Y, King TC, Steiner A, Muresan NM, Gan L, Wright DS, Reisner E
Chem Commun (Camb), 2013, 39, 4331-4333. DOI: 10.1039/C2CC34934E


Formation of Ti28 ln cages, the highest nuclearity polyoxotitanates (Ln = La, Ce).
Lv Y, Willkomm J, Leskes M, Steiner A, King TC, Gan L, Reisner E, Wood PT, Wright DS
Chemistry, 2012, 38, 11867-11870. DOI: 10.1002/chem.201201827


Main group pyridyl-based ligands; strategies to mixed metal complexes.
Simmonds HR, Wright DS
Chem Commun (Camb), 2012, 69, 8617-8624. DOI: 10.1039/C2CC33015F


Group 11 complexes containing the [C5(CN)5]- ligand; 'coordination-analogues' of molecular organometallic systems.
Less RJ, Guan B, Muresan NM, McPartlin M, Reisner E, Wilson TC, Wright DS
Dalton Trans, 2012, 19, 5919-5924. DOI: 10.1039/C2DT30274H


Encapsulation of a 'naked' Br- anion in a polyoxotitanate host
Lv Y, Willkomm J, Steiner A, Gan L, Reisner E, Wright DS
CHEMICAL SCIENCE, 2012, 8, 2470-2473. DOI: 10.1039/C2SC20193C


Royal Society of Chemistry Awards
Stephan DW, Wright DS, Atwood JL, Cloke FGN, Tsang SCE, Lehn J-M, Moody CJ, O'Reilly RK, Taylor RJK, Houk KN, Colacot TJ
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 37, 9214-9215. DOI: 10.1002/anie.201205769


Group 2 (Be-Ba) and group 12 (Zn-Hg)
Dane SBJ, King TC, Wright DS
Organometallic Chemistry, 2012, 112-127.


A self-template synthesis of hierarchical porous carbon foams based on banana peel for supercapacitor electrodes
Lv Y, Gan L, Liu M, Xiong W, Xu Z, Zhu D, Wright DS
Journal of Power Sources, 2012, 152-157.


Catalytic versus stoichiometric dehydrocoupling using main group metals
Less RJ, Melen RL, Wright DS
RSC ADV, 2012, 6, 2191-2199. DOI: 10.1039/c2ra00882c


Structure and bonding of the manganese(II) phosphide complex (t-BuPH 2)(ν 5-Cp)Mn{μ-(t-BuPH)} 2Mn(Cp)(t- BuPH 2)
Stokes FA, Less RJ, Haywood J, Melen RL, Thompson RI, Wheatley AEH, Wright DS, Johansson AJ, Kloo L
Organometallics, 2012, 1, 23-26.


Structure and Bonding of the Manganese(II) Phosphide Complex (t-BuPH2)(eta(5)-Cp)Mn{mu-(t-BuPH)}(2)Mn(Cp)(t-BuPH2)
Stokes FA, Less RJ, Haywood J, Melen RL, Thompson RI, Wheatley AEH, Wright DS, Johansson AJ, Kloo L
ORGANOMETALLICS, 2012, 1, 23-26. DOI: 10.1021/om200381p

2011


Transition metal complexes of the pentacyanocyclopentadienide anion.
Less RJ, Wilson TC, McPartlin M, Wood PT, Wright DS
Chem Commun (Camb), 2011, 36, 10007-10009. DOI: 10.1039/C1CC13021H


Extending the family of titanium heterometallic-oxo-alkoxy cages.
Eslava S, Goodwill BP, McPartlin M, Wright DS
Inorg Chem, 2011, 12, 5655-5662. DOI: 10.1021/ic200350j


Oxidative dehydrocoupling of N-H bonds using a redox-active main group superbase.
Less RJ, Naseri V, McPartlin M, Wright DS
Chem Commun (Camb), 2011, 21, 6129-6131. DOI: 10.1039/C1CC00053E


A quadruply-bonded [Cr2(guanidinate)4]4- tetraanion.
Haywood J, Stokes FA, Less RJ, McPartlin M, Wheatley AE, Wright DS
Chem Commun (Camb), 2011, 14, 4120-4122. DOI: 10.1039/C1CC10194C


An unexpected dependence on the SnII base; reactions of Sn(NR2)2 with aromatic dithiols.
Melen RL, McPartlin M, Wright DS
Dalton Trans, 2011, 8, 1649-1651. DOI: 10.1039/C0DT01690J


Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3.
Cowley HJ, Holt MS, Melen RL, Rawson JM, Wright DS
Chem Commun (Camb), 2011, 9, 2682-2684. DOI: 10.1039/C0CC05294A


Group 2 (Be-Ba) and Group 12 (Zn-Hg)
Less RJ, Melen RL, Wright DS
Organometallic Chemistry, 2011, 100-114.


Group 13 BN dehydrocoupling reagents, similar to transition metal catalysts but with unique reactivity
Hansmann MM, Melen RL, Wright DS
CHEM SCI, 2011, 8, 1554-1559. DOI: 10.1039/C1SC00154J


Assembly of the first fullerene-type metal-organic frameworks using a planar five-fold coordination node
Bacsa J, Less RJ, Skelton HE, Soracevic Z, Steiner A, Wilson TC, Wood PT, Wright DS
Angewandte Chemie - International Edition, 2011, 36, 8279-8282.

2010


Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity.
García F, Less RJ, McPartlin M, Michalski A, Mulvey RE, Naseri V, Stead ML, Morán de Vega A, Wright DS
Chem Commun (Camb), 2011, 6, 1821-1823. DOI: 10.1039/C0CC04483K


The First-Row Transition Metal Interstitial Hydride Anion [{PhP(CH2)(3)Fe}(4)(mu(4)-H)](-)
Serrano CB, Less RJ, McPartlin M, Naseri V, Wright DS
ORGANOMETALLICS, 2010, 22, 5754-5756. DOI: 10.1021/om100838u


Single-source materials for metal-doped titanium oxide: syntheses, structures, and properties of a series of heterometallic transition-metal titanium oxo cages.
Eslava S, McPartlin M, Thomson RI, Rawson JM, Wright DS
Inorg Chem, 2010, 24, 11532-11540. DOI: 10.1021/ic101687m


A simple approach to coordination compounds of the pentacyanocyclopentadienide anion.
Less RJ, McPartlin M, Rawson JM, Wood PT, Wright DS
Chemistry, 2010, 46, 13723-13728. DOI: 10.1002/chem.201001980


Synthesis, Characterization, and Surface Tethering of Sulfide-Functionalized Ti-16-oxo-alkoxy Cages
Eslava S, Papageorgiou AC, Beaumont SK, Kyriakou G, Wright DS, Lambert RM
CHEM MATER, 2010, 18, 5174-5178. DOI: 10.1021/cm101039k


Heterometallic metal-titanium(IV) oxo cages: Key building blocks for hybrid materials
Eslava S, Hengesbach F, McPartlin M, Wright DS
ABSTR PAP AM CHEM S, 2010, -.


Synthesis, characterization and Au surface tethering of Ti-16-oxo-alkoxy cages
Eslava S, Papageorgiou AC, Beaumont SK, Kyriakou G, Wright DS, Lambert RM
ABSTR PAP AM CHEM S, 2010, -.


Formation and rearrangement of Sn(II) phosphanediide cages.
McPartlin M, Melen RL, Naseri V, Wright DS
Chemistry, 2010, 29, 8854-8860. DOI: 10.1002/chem.201000656


Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines.
Naseri V, Less RJ, Mulvey RE, McPartlin M, Wright DS
Chem Commun (Camb), 2010, 27, 5000-5002. DOI: 10.1039/c0cc00827c


Heterometallic cobalt(II)-titanium(IV) oxo cages; key building blocks for hybrid materials.
Eslava S, Hengesbach F, McPartlin M, Wright DS
Chem Commun (Camb), 2010, 26, 4701-4703. DOI: 10.1039/c0cc00016g


Syntheses and structures of [Me2Si{As((PBu)-Bu-t)(3)}(2)] and [(CyP)(3)SiMe2] (Cy = cyclohexyl, C6H11)
Chan WTK, Garcia F, McPartlin M, Melen RL, Wright DS
J ORGANOMET CHEM, 2010, 7, 1069-1073. DOI: 10.1016/j.jorganchem.2009.12.011


Macrocyclic phosphazane ligands
Calera SG, Wright DS
DALTON T, 2010, 21, 5055-5065. DOI: 10.1039/b926428k


Group 2 (Be-Ba) and group 12 (Zn-Hg)
Bullock TH, Melen RL, Wright DS
Organometallic Chemistry, 2010, 168-181.

2009


The regioselective photochemical rearrangement of alpha-[PN(t)Bu](4).
Bladt H, Gonzalez Calera S, Goodman JM, Less RJ, Naseri V, Steiner A, Wright DS
Chem Commun (Camb), 2009, 43, 6637-6639. DOI: 10.1039/b914370j


Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene
Kennedy AR, Klett J, Mulvey RE, Wright DS
SCIENCE, 2009, 5953, 706-708. DOI: 10.1126/science.1178165


Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene
Alan R Kennedy, Jan Klett, Robert E Mulvey, Dominic S Wright
Science DOI: 10.1126/science.1181863


Synergic anion and cation coordination using the tripodal aluminate anion [MeAl(2-py)(3)](-) (py = 2-pyridyl).
Bullock TH, Chan WT, Wright DS
Dalton Trans, 2009, 34, 6709-6711. DOI: 10.1039/b909933f


Recent perspectives on main group-mediated dehydrocoupling of P-P bonds.
Less RJ, Melen RL, Naseri V, Wright DS
Chem Commun (Camb), 2009, 33, 4929-4937. DOI: 10.1039/b907823a


The Carbanionic Phosphoylide Dianion [PhP(CH2)(3)](2-), Isoelectronic with Phosphonate Dianions [RP(O)(3)](2-)
Less RJ, Naseri V, Wright DS
ORGANOMETALLICS, 2009, 13, 3594-3596. DOI: 10.1021/om9001704


Formation of an Organometallic Phosphanediide via Main-Group Dehydrocoupling
Less RJ, Naseri V, Wright DS
ORGANOMETALLICS, 2009, 7, 1995-1997. DOI: 10.1021/om9000296


Metal and ligand substitution of the aluminium tris-pyridyl ligands [RAl(2-py')(3)](-) (R = Et, (n)Bu, (s)Bu, (t)Bu; 2-py' = 2-pyridyl, 3-methyl-2-pyridyl, 5-methyl-2-pyridyl, 6-methyl-2-pyridyl).
Bullock TH, Chan WT, Eisler DJ, Streib M, Wright DS
Dalton Trans, 2009, 6, 1046-1054. DOI: 10.1039/b815057e


Joining the crown family; the tetrameric, O-bridged macrocycle [{P(mu-(NBu)-Bu-t)}(2)(mu-O)](4)
Calera SG, Eisler DJ, Goodman JM, McPartlin M, Singh S, Wright DS
DALTON T, 2009, 8, 1293-1296. DOI: 10.1039/b900268p


Joining the crown family; the tetrameric, O-bridged macrocycle [{P(micro-N(t)Bu)}2(micro-O)]4.
Gonzalez Calera S, Eisler DJ, Goodman JM, McPartlin M, Singh S, Wright DS
Dalton Trans, 2009, 8, 1293-1296.


Structurally Defined Potassium-Mediated Zincation of Pyridine and 4-R-Substituted Pyridines (R = Et, iPr, tBu, Ph, and Me2N) by Using Dialkyl-TMP-Zincate Bases
Clegg W, Conway B, Graham DV, Hevia E, Kennedy AR, Mulvey RE, Russo L, Wright DS
CHEM-EUR J, 2009, 29, 7074-7082. DOI: 10.1002/chem.200900549


Group 2 (Be-Ba) and group 12 (Zn-Hg)
García F, Wright DS
Organometallic Chemistry, 2009, 162-182.


Formation of a new class of 7 pi radicals via sterically induced P-P bond cleavage of the dimers [(CH)(2)(NR)(2)P](2)
Edge R, Less RJ, McInnes EJL, Muther K, Naseri V, Rawson JM, Wright DS
CHEM COMMUN, 2009, 13, 1691-1693. DOI: 10.1039/b821241d

2008


Synthesis and structure of the Li13 cage [[[O-P(mu-NtBu)]2Li2]3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [O-P(mu-NtBu)]2(2-) dianion.
Chan WT, Eisler D, García F, Gonzalez-Calera S, McPartlin M, Morey JV, Mulvey RE, Singh S, Steiner A, Wright DS
Chem Commun (Camb), 2008, 19, 2251-2253. DOI: 10.1039/b800051d


The 6pi, phosphide-stabilised stannylene dianion [C6H4P2Sn]2-; the first member of a new class of Arduengo-type carbene analogues.
Eisler DJ, Less RJ, Naseri V, Rawson JM, Wright DS
Dalton Trans, 2008, 18, 2382-2384. DOI: 10.1039/b800501j


pi-Bonding versus oligomerisation in the aromatic anions [C(6)H(4)N(2)E](-): formation of the cyclic tetrameric tetraanion [C(6)H(4)N(2)Sb](4)(4-).
García F, Less RJ, Naseri V, McPartlin M, Rawson JM, Wright DS
Dalton Trans, 2008, 8, 997-999. DOI: 10.1039/b718512j


Direct synthesis of the 1,2,3-[C6H4P...P...P]- anion, isoelectronic with the indenyl anion [C6H4CH...CH...CH]-.
García F, Less RJ, Naseri V, McPartlin M, Rawson JM, Sancho Tomas M, Wright DS
Chem Commun (Camb), 2008, 7, 859-861. DOI: 10.1039/b718425e


The selenium-based hexameric macrocycle [(Se==)P(mu-NtBu)2P(mu-Se)]6.
González-Calera S, Eisler DJ, Morey JV, McPartlin M, Singh S, Wright DS
Angew Chem Int Ed Engl, 2008, 6, 1111-1114. DOI: 10.1002/anie.200703981


Group 2 (Be-Ba) and group 12 (Zn-Hg)
García F, Wright DS
Organometallic Chemistry, 2008, 92-110.


[{(18-crown-6)K}GaCl4](infinity), a diamondoid structure templated by tetrahedral GaCl4- ions
Chan WTK, Eisler DJ, Wright DS
CRYSTENGCOMM, 2008, 10, 1315-1317. DOI: 10.1039/b807523a


Manganese(II)-lithium and -sodium inverse crown ether (ICE) complexes.
Kennedy AR, Klett J, Mulvey RE, Newton S, Wright DS
Chem Commun (Camb), 2008, 3, 308-310.


Manganese(II)-lithium and -sodium inverse crown ether (ICE) complexes
Kennedy AR, Klett J, Mulvey RE, Newton S, Wright DS
CHEM COMMUN, 2008, 3, 308-310. DOI: 10.1039/b714880a


A mechanistic study of the C-P bond cleavage reaction of 1,2-(PH2)(2)-C6H4 with (BuLi)-Bu-n/Sb(NMe2)(3)
Edge R, Less RJ, Naseri V, McInnes EJL, Mulvey RE, Wright DS
DALTON T, 2008, 45, 6454-6460. DOI: 10.1039/b810028d

2007


Effective visible light-activated B-doped and B,N-codoped TiO2 photocatalysts.
In S, Orlov A, Berg R, García F, Pedrosa-Jimenez S, Tikhov MS, Wright DS, Lambert RM
J Am Chem Soc, 2007, 45, 13790-13791. DOI: 10.1021/ja0749237


Cyclophosphazenes tethered together via N-ring centres with ortho-, meta- and para-xylylene linkers
Benson MA, Boomishankar R, Wright DS, Steiner A
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 13, 2768-2772. DOI: 10.1016/j.jorganchem.2006.11.052


Syntheses and structures of the heterometallic complexes [{MeIn(μ-PCy)}2(μ-PCy)]2(Li · Et2O)4, [Me2In(PhMes)2]-[Li(TMEDA)2] +
Fanjul I, García F, Kowenicki RA, Mosquera MEG, McPartlin M, Wright DS
Inorganica Chimica Acta, 2007, 4, 1266-1273.


Pyridyl 'ring-flipping' in the dimers [Me2E(2-py)]2 (E=B, Al, Ga; 2-py=2-pyridyl).
García F, Hopkins AD, Kowenicki RA, McPartlin M, Silvia JS, Rawson JM, Rogers MC, Wright DS
Chem Commun (Camb), 2007, 6, 586-588. DOI: 10.1039/b613748b


Structural, solid-state NMR and theoretical studies of the inverse-coordination of lithium chloride using group 13 phosphide hosts.
Duer MJ, García F, Goodman JM, Hehn JP, Kowenicki RA, Naseri V, McPartlin M, Stead ML, Stein R, Wright DS
Chemistry, 2007, 4, 1251-1260. DOI: 10.1002/chem.200600781


Reactions of Sn(NMe2)2 with MPHCy: the effects of alkali metal phosphide coupling (Cy=cyclohexyl; M=Li, Na, K, Rb).
Alvarez P, García F, Hehn JP, Kraus F, Lawson GT, Korber N, Mosquera ME, McPartlin M, Moncrieff D, Pask CM, Woods AD, Wright DS
Chemistry, 2007, 4, 1078-1089. DOI: 10.1002/chem.200600633


Group 2 (Be-Ba) and group 12 (Zn-Hg)
García F, Wright DS
Organometallic Chemistry, 2007, 22-37.


An unexpected pathway in the cage opening and aggregation of P4.
Chan WT, García F, Hopkins AD, Martin LC, McPartlin M, Wright DS
Angew Chem Int Ed Engl, 2007, 17, 3084-3086. DOI: 10.1002/anie.200604267


Formation and structure of the [(1,2-C(6)H(4)P(2)Sb)(2)](4-) ion: implications for an extended family of isoelectronic main-group radicals.
García F, Less RJ, Naseri V, McPartlin M, Rawson JM, Wright DS
Angew Chem Int Ed Engl, 2007, 41, 7827-7830. DOI: 10.1002/anie.200702603


Trapping of oligomeric cyclopentadienyllithium cationic and anionic fragments by a V=V-bonded ligand
Fernandez-Cortabitarte C, Garcia F, Morey JV, McPartlin M, Singh S, Wheatley AEH, Wright DS
ANGEW CHEM INT EDIT, 2007, 28, 5425-5427. DOI: 10.1002/anie.200700925


Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)](2) and the unusual manganate cage [LiMn(hpp)(3)](2) (hppH=1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2,a] pyrimidine)
Brinkmann C, Garcia F, Morey JV, McPartlin M, Singh S, Wheatley AEH, Wright DS
DALTON T, 2007, 16, 1570-1572. DOI: 10.1039/b700409e

2006


Efficient visible light-active N-doped TiO2 photocatalysts by a reproducible and controllable synthetic route.
In S, Orlov A, García F, Tikhov M, Wright DS, Lambert RM
Chem Commun (Camb), 2006, 40, 4236-4238. DOI: 10.1039/b610316b


Targeting large phosp(III)azane macrocyles [{P(mu-NR)}(2)(LL)](n) (n>or = 2).
Dodds F, García F, Kowenicki RA, Parsons SP, McPartlin M, Wright DS
Dalton Trans, 2006, 35, 4235-4243. DOI: 10.1039/b607332h


Reactions of Sn(NMe2)(2) with alkali-metal tert-butylphosphides (BuPHM)-Bu-t (M = Li, Na, K): Evidence for metal-induced modification of the tin(II) phosphinidene anions
Garcia F, Hehn JP, Kowenicki RA, McPartlin M, Pask CM, Rothenberger A, Stead ML, Wright DS
ORGANOMETALLICS, 2006, 13, 3275-3281. DOI: 10.1021/om060167m


Syntheses and structure of heterometallic complexes containing tripodal group 13 ligands [RE(2-py)(3)](-) (E = Al, Ln)
Garcia F, Hopkins AD, Kowenicki RA, McPartlin M, Rogers MC, Silvia JS, Wright DS
ORGANOMETALLICS, 2006, 10, 2561-2568. DOI: 10.1021/om0600691


A structural and magnetic study of organolanthanide(III) amides.
Layfield RA, Bashall A, McPartlin M, Rawson JM, Wright DS
Dalton Trans, 2006, 13, 1660-1666. DOI: 10.1039/b514470a


"Structural and magnetic studies of the tris(cyclopentadienyl)manganese(II) ""paddle-wheel"" anions [Cp(3-n)(MeCp)(n)Mn](-) (n=0-3, MeCp=C(5)H(4)CH(3), Cp=C(5)H(5))."
Alvarez CS, Bashall A, McInnes EJ, Layfield RA, Mole RA, McPartlin M, Rawson JM, Wood PT, Wright DS
Chemistry, 2006, 11, 3053-3060. DOI: 10.1002/chem.200501214


Adventures in Tin(II) phosphinidene chemistry; insights into the mechanism of P-P and Sn-Sn bond formation
Garcia F, Stead ML, Wright DS
J ORGANOMET CHEM, 2006, 8, 1673-1680. DOI: 10.1016/j.jorganchem.2005.11.067

2005


The first complex of the pentameric phosphazane macrocycle [{P(μ-N tBu)}2(μ-NH)]5 with a neutral molecular guest: Synthesis and structure of [{P(μ-NtBu)}2(μ- NH)]5(CH2Cl2)2
García F, Kowenicki RA, Kuzu I, McPartlin M, Riera L, Wright DS
Inorganic Chemistry Communications, 2005, 11, 1060-1062.


The folded, tetrameric phosph(III)azane macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4.
Dodds F, García F, Kowenicki RA, McPartlin M, Riera L, Steiner A, Wright DS
Chem Commun (Camb), 2005, 40, 5041-5043. DOI: 10.1039/b510636b


Inverse coordination of an ionic lattice by a metal host.
Duer MJ, García F, Kowenicki RA, Naseri V, McPartlin M, Stead ML, Stein RS, Wright DS
Angew Chem Int Ed Engl, 2005, 35, 5729-5733. DOI: 10.1002/anie.200501198


Triphosph(III)azanes to diphosph(III)azanes; a cracking transformation.
García F, Kowenicki RA, Riera L, Wright DS
Dalton Trans, 2005, 15, 2495-2496. DOI: 10.1039/b505720e


Synthesis and structure of the calixarene-like phosph(III)azane macrocycle [{P(mu-N(t)Bu)}2{1,5-(NH)2C10H6}]3.
Dodds F, García F, Kowenicki RA, McPartlin M, Steiner A, Wright DS
Chem Commun (Camb), 2005, 29, 3733-3735. DOI: 10.1039/b504686f


Quadruple deprotonation of 2-aminophenylphosphane with a p-block-metal/alkali-metal base.
García F, Humphrey SM, Kowenicki RA, McInnes EJ, Pask CM, McPartlin M, Rawson JM, Stead ML, Woods AD, Wright DS
Angew Chem Int Ed Engl, 2005, 22, 3456-3459. DOI: 10.1002/anie.200500340


Selection of the cis and trans phosph(III)azane macrocycles [{P(mu-NtBu)}2(1-Y-2-NH-C6H4)]2(Y=O, S).
Garcia F, Goodman JM, Kowenicki RA, McPartlin M, Riera L, Silva MA, Wirsing A, Wright DS
Dalton Trans, 2005, 10, 1764-1773. DOI: 10.1039/b502200b


Reactions of Sn(NMe2)(2) with primary aryl phosphides, ArPH-: Synthesis and structures of the heteroleptic cages [{(PhP-PPh)Sn(mu-PPh}(2)(Na center dot PMDETA)(4) and [{Sn(mu(3)-Ppy)}(3){Sn(mu(3),mu(1)-pyP-Ppy)}(3)]
Garcia F, Hopkins AD, Kowenicki RA, McPartlin M, Pask CM, Stead ML, Woods AD, Wright DS
ORGANOMETALLICS, 2005, 8, 1813-1818. DOI: 10.1021/om049177i


Highly selective epoxidation of styrene using a transition metal-aluminium(III) complex containing the [MeAl(2-py)3]- anion (2-py = 2-pyridyl).
Alvarez CS, García F, Humphrey SM, Hopkins AD, Kowenicki RA, McPartlin M, Layfield RA, Raja R, Rogers MC, Woods AD, Wright DS
Chem Commun (Camb), 2005, 2, 198-200. DOI: 10.1039/b413488e


Reactions of Sn(NMe2)2 with primary aryl phosphides, ArPH-: Synthesis and structures of the heteroleptic cages {(PhP-PPh)Sn(μ-PPh)}2(Na-PMDETA)4 and [{Sn(μ3-Ppy)}2{Sn(μ3,μ1- pyP-Ppy)}3]
García F, Hopkins AD, Kowenicki RA, McPartlin M, Pask CM, Stead ML, Woods AD, Wright DS
Organometallics, 2005, 8, 1813-1818.

2004


Selection of a pentameric host in the host-guest complexes [[[[P(mu-NtBu)]2(mu-NH)]5].I]-[Li(thf)4]+ and [[[P(mu-NtBu)]2(mu-NH)]5].HBr.THF.
García F, Goodman JM, Kowenicki RA, Kuzu I, McPartlin M, Silva MA, Riera L, Woods AD, Wright DS
Chemistry, 2004, 23, 6066-6072. DOI: 10.1002/chem.200400320


Syntheses, structures and magnetic properties of Mn(II) dimers [CpMn(micro-X)]2(Cp = C5H5; X = RNH, R1R2N, C[triple bond]CR).
Alvarez CS, Boss SR, Burley JC, Humphry SM, Layfield RA, Kowenicki RA, McPartlin M, Rawson JM, Wheatley AE, Wood PT, Wright DS
Dalton Trans, 2004, 21, 3481-3487. DOI: 10.1039/B409135C


The formation of dimeric phosph(III)azane macrocycles [[P(mu-NtBu)]2.LL]2 [LL = organic spacer].
García F, Kowenicki RA, Kuzu I, Riera L, McPartlin M, Wright DS
Dalton Trans, 2004, 18, 2904-2909. DOI: 10.1039/B409071C


Synthesis of the [MeAl(2-py)(3)](-) anion and its application as a stable and mild pyridyl-transfer reagent (2-py=2-pyridyl)
Garcia F, Hopkins AD, Kowenicki RA, McPartlin M, Rogers MC, Wright DS
ORGANOMETALLICS, 2004, 16, 3884-3890. DOI: 10.1021/om049749z


thermodynamic/kinetic control in the isomerization of the [[tBuNP(mu-NtBu)]2]2- ion.
Bond AD, Doyle EL, García F, Kowenicki RA, Moncrieff D, McPartlin M, Riera L, Woods AD, Wright DS
Chemistry, 2004, 9, 2271-2276. DOI: 10.1002/chem.200305762


Selective formation of the [PhP(H)-PPh]- anion in the reaction of PhPHLi with MeAlCl(2); synthesis and structure of the unusual tetramer [(PhP(H)-PPh)Li.thf]4.
Garcia F, Humphrey SM, Kowenicki RA, McPartlin M, Wright DS
Dalton Trans, 2004, 7, 977-979. DOI: 10.1039/b402295e


A new low-temperature synthesis of zintl compounds
Hopkins AD, Wright DS
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2004-04, 04-May, 737-742. DOI: 10.1080/10426500490426719


Steric control in the oligomerisation of phosphazane dimers; towards new phosphorus-nitrogen macrocycles.
Doyle EL, García F, Humphrey SM, Kowenicki RA, Riera L, Woods AD, Wright DS
Dalton Trans, 2004, 5, 807-812. DOI: 10.1039/b314790h


The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl).
García F, Hopkins AD, Humphrey SM, McPartlin M, Rogers MC, Wright DS
Dalton Trans, 2004, 3, 361-362. DOI: 10.1039/b315503j


Synthesis and structure of [{Sn2(μ-PMes)3}K 2·3THF]∞, exhibiting multifunctional coordination of [Sn2(μ-PMes)3]2- Anions to K+
García F, Hopkins AD, Humphrey SM, McPartlin M, Pask CM, Woods AD, Wright DS
Organometallics, 2004, 21, 4821-4823.


Reductive-elimination of phosphide units; the basis of a general approach to a range of alloys and materials
Garcia F, Hopkins AD, Pask CM, Woods AD, Wright DS
JOURNAL OF MATERIALS CHEMISTRY, 2004, 21, 3093-3100. DOI: 10.1039/b406793b


Group 2 (Be-Ba) and group 12 (Zn-Hg)
Wright DS
Organometallic Chemistry, 2004, 70-84.

2003


Exo-metal coordination by a tricyclic [{P(μN-2-NC5H 4)}2(μ-O)]2 dimer in [{P(μ-N-2-NC 5H4)}2(μ-O)]2{CuCl·(C 5H5N)2}4 {2-NC5H 4 = 2-pyridyl, C5H5N = pyridine
Bond AD, Doyle EL, García F, Kowenicki RA, McPartlin M, Riera L, Wright DS
Chemical Communications, 2003, 24, 2990-2991.


Primary amido and phosphido complexes of zinc: potential precursors to heterometallic arrangements
Bashall A, Cole JM, Garcia F, Primo A, Rothenberger A, McPartlin M, Wright DS
INORG CHIM ACTA, 2003, 41-48. DOI: 10.1016/S0020-1693(03)00375-X


Toroidal main group macrocycles: New opportunities for cation and anion coordination
Doyle EL, Riera L, Wright DS
EUR J INORG CHEM, 2003, 18, 3279-3289. DOI: 10.1002/ejic.200200688


Synthesis and structure of [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf, containing a [MeAl(mu-PMes)(PMes)]2(4-) tetraanion (Mes = 2,4,6-Me3C6H2).
García F, Haigh R, McPartlin M, Wright DS
Chem Commun (Camb), 2003, 16, 2052-2053.


"Synthesis and structure of the novel ""paddle-wheel"" complex [(eta(5)-Cp)(2)Pb(mu :eta(5)-Cp)K}center dot 2THF]"
Layfield RA, McPartlin M, Wright DS
ORGANOMETALLICS, 2003, 12, 2528-2530. DOI: 10.1021/om030126f


Synthesis and structure of [(Sn(mu-PCy))3(Na x PMDETA)2], containing an electron-deficient [(Sn(mu-PCy))3]2- dianion.
Alvarez-Bercedo P, Bond AD, Haigh R, Hopkins AD, Lawson GT, McPartlin M, Moncrieff D, Mosquera ME, Rawson JM, Woods AD, Wright DS
Chem Commun (Camb), 2003, 11, 1288-1289.


Applications of manganocene in the synthesis of Mn(II) amide and imide cages
Alvarez CS, Bashall A, Bond AD, Cave D, Harron EA, Layfield RA, Mosquera MEG, McPartlin M, Rawson JM, Wood PT, Wright DS
DALTON T, 2003, 15, 3002-3008. DOI: 10.1039/b303727b


"Synthesis and structure of the novel ""paddle-wheel"" complex [{(η5-Cp)2Pb(μ:η5-Cp)K}̇2THF]"
Layfield RA, McPartlin M, Wright DS
Organometallics, 2003, 12, 2528-2530.


Synthesis and structure of [{Sn(mu-PCy)}(3)(Na center dot PMDETA)(2)], containing an electron-deficient [{Sn(mu-PCy)}(3)](2-) dianion
Alvarez-Bercedo P, Bond AD, Haigh R, Hopkins AD, Lawson GT, McPartlin M, Moncrieff D, Mosquera MEG, Rawson JM, Woods AD, Wright DS
CHEM COMMUN, 2003, 11, 1288-1289. DOI: 10.1039/b300522d


Stabilisation of an ortho-deprotonated mesityl group within the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn](3)(-) stannate ion
McPartlin M, Woods AD, Pask CM, Vogler T, Wright DS
CHEM COMMUN, 2003, 13, 1524-1525. DOI: 10.1039/b303390m


Reactions of metallated cyclohexyl phosphine (CyPHM) with As(NMe2)(3); synthesis of [(CyP)(4)As](-) anions (M = Li or Na, Cy = cyclohexyl)
Bashall A, Garcia F, Hopkins AA, Wood JA, McPartlin M, Woods AD, Wright DS
DALTON T, 2003, 6, 1143-1147. DOI: 10.1039/b211037g


Group 15 element imido and phosphido cages; Coordination chemistry and synthetic applications
Doyle EL, Hopkins AD, Lawson GT, McPartlin M, Woods AD, Wright DS
PERSPECTIVES IN ORGANOMETALLIC CHEMISTRY, 2003, 287, 1-15.

2002


Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(mu 4-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5).
Alvarez CS, Bond AD, Cave D, Mosquera ME, Harron EA, Layfield RA, McPartlin M, Rawson JM, Wood PT, Wright DS
Chem Commun (Camb), 2002, 24, 2980-2981.


"Suggestion of a ""twist"" mechanism in the oligomerisation of a dimeric phospha(III)zane: Insights into the selection of adamantoid and macrocyclic alternatives"
Bashall A, Doyle EL, Garcia F, Lawson GT, Linton DJ, Moncrieff D, McPartlin M, Woods AD, Wright DS
CHEM-EUR J, 2002, 24, 5723-5731.


Formation and decomposition of the Sb(III)/Li cage [{Sb(P-t-BU)3}2Li6·6thf]
Bashall A, García F, Lawson GT, McPartlin M, Rothenberger A, Woods AD, Wright DS
Canadian Journal of Chemistry, 2002, 11, 1421-1427.


Templating and selection in the formation of macrocycles containing [{P(mu-NtBu)(2)}(mu-NH)](n) frameworks: Observation of halide ion coordination
Bashall A, Bond AD, Doyle EL, Garcia F, Kidd S, Lawson GT, Parry MC, McPartlin M, Woods AD, Wright DS
CHEM-EUR J, 2002, 15, 3377-3385.


Synthesis of a deca-lithium cage containing an [(RN)2As(mu-NR)As(NR)2]4- tetraanion; a homologue of group 15 trianions of the type [E(NR)3]3-.
Bond AD, García F, Jantos K, Lawson GT, McPartlin M, Wright DS
Chem Commun (Camb), 2002, 12, 1276-1277.


Interpreting molecular crystal disorder in plumbocene, Pb(C5H5)(2): Insight from theory
Morrison CA, Wright DS, Layfield RA
J AM CHEM SOC, 2002, 23, 6775-6780. DOI: 10.1021/ja025709f


A new, tetragonal, helical phase of plumbocene, Cp2Pb; variations on a molecular string (Cp = C5H5)
Layfield RA, Morrison CA, Wright DS
J ORGANOMET CHEM, 2002, 01-Feb, 75-76.


Formation of double cubanes [Sn-7(NR)(8)] in the reactions of pyridyl and pyrimidinyl amines with Sn(NMe2)(2) : A synthetic and theoretical study
Armstrong DR, Benevelli F, Bond AD, Feeder N, Harron EA, Hopkins AD, McPartlin M, Moncrieff D, Saez D, Quadrelli EA, Woods AD, Wright DS
INORG CHEM, 2002, 6, 1492-1501. DOI: 10.1021/ic011090r


Synthesis, structures and coordination behaviour of [As(NR)(3)](3-) trianions
Bashall A, Bond AD, Hopkins AD, Kidd SJ, McPartlin M, Steiner A, Wolf R, Woods AD, Wright DS
J CHEM SOC DALTON, 2002, 3, 343-351. DOI: 10.1039/b106913f


Syntheses and structures of the cubanes [PhOSb(mu(3)-NCy)](4) and [pyOBi(mu(3)-NCy)](4) (Cy = cyclohexyl, py=2-pyridyl)
Bickley JF, Bond AD, Garcia F, Jantos K, Lawson GT, McPartlin M, Steiner A, Wright DS
J CHEM SOC DALTON, 2002, 24, 4629-4633. DOI: 10.1039/b208302g


Nucleophilic addition to a Sn(II) imido cubane, [SnNR](4); a new route to heteroleptic stannates
Bond AD, Harron EA, Lawson GT, Mosquera MEG, McPartlin M, Wright DS
J CHEM SOC DALTON, 2002, 18, 3525-3528. DOI: 10.1039/b204340h


Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]3 3- trianion
García F, Linton DJ, McPartlin M, Rothenberger A, Wheatley AEH, Wright DS
Journal of the Chemical Society, Dalton Transactions, 2002, 4, 481-483.


Armstrong DR, Ball SC, Barr D, Clegg W, Linton DJ, Kerr LC, Moncrieff D, Raithby PR, Singer RJ, Snaith R, Stalke D, Wheatley AEH, Wright DS
Journal of the Chemical Society-Dalton Transactions, 12, -. DOI: 10.1039/B107970k


Effects of meta-substitution on aggregation in the cubanes [SnNR](4) {R = [2-Me-5-MeOC6H3], [2,5-(MeO)(2)C6H3] and [3,5-(MeO)(2)C6H3]}
Bashall A, Ciulli A, Harron EA, Lawson GT, McPartlin M, Mosquera MEG, Wright DS
J CHEM SOC DALTON, 2002, 6, 1046-1050. DOI: 10.1039/b107425c

2001


The tetrameric macrocycle [{P(μ-NtBu)}2NH]4
Bashall A, Doyle EL, Tubb C, Kidd SJ, McPartlin M, Woods AD, Wright DS
Chemical Communications, 2001, 24, 2542-2543.


Methyl group transfer from ZnMe2 to arsenic(III), an alternative pathway to deprotonation of [CyNHAs(mu-NCy)](2)
Bond AD, Hopkins AD, Rothenberger A, Wolf R, Woods AD, Wright DS
ORGANOMETALLICS, 2001, 22, 4454-4456.


The first observation of the [Cp3Mn](-) anion; structures of hexagonal [(eta(2)-Cp)(3)MnK center dot 1.5thf] and ion-separated [(eta(2)-Cp)(3)Mn](2)[Mg(thf)(6)]center dot 2thf
Bond AD, Layfield RA, MacAllister JA, McPartlin M, Rawson JM, Wright DS
CHEM COMMUN, 2001, 19, 1956-1957.


Synthesis and structure of the octanuclear manganese(II) cage [(eta-Cp)Mn{2-NH(4,6-Me(2)pm)center dot Mn{2-N(4,6-Me2Pm)}](4) (Cp = C5H5, pm = pyrimidine)
Aluarez CS, Bond AD, Harron EA, Layfield RA, McAllister JA, Pask CM, Rawson JM, Wright DS
ORGANOMETALLICS, 2001, 20, 4135-4137. DOI: 10.1021/om010357r


Phosphinidine complexes of p block metals; new routes to cyclic ligands and Zintl phases
Hopkins AD, Wood JA, Wright DS
COORDINATION CHEMISTRY REVIEWS, 2001-06, 155-172.


Synthesis and structure of [Sn-9(Ndmp)(7)(HNdmp)(2)O-2], containing a bidentate double-cubane oxo fragment (H(2)Ndmp=2-amino-4,6-dimethoxypyrimidine
Feeder N, Harron EA, Mosquera MEG, Woods AD, Wright DS
CHEM COMMUN, 2001, 11, 1010-1011.


Synthesis and structure of [{Sn-4(NBut)(3)P}{Sn-4(NBut)(3)(OSiMe3)}]; a low-oxidation state p-block metal complex containing a P3- anion
Mosquera MEG, Hopkins AD, Raithby PR, Steiner A, Rothenberger A, Woods AD, Wright DS
CHEM COMMUN, 2001, 4, 327-328.


Phosphide coupling in the reaction of Sn(NMe2)(2) with MesPHLi; synthesis and structure of the Sn(II) phosphide dianion [{Sn(mu-PMes)}(2)(MesP)(2)](2-) (Mes=2,4,6-Me3C6H2)
Bond AD, Rothenberger A, Woods AD, Wright DS
CHEM COMMUN, 2001, 6, 525-526.


Group 2 (Be-Ba) and group 12 (Zn-Hg)
Layfield RA, Wright DS
Organometallic Chemistry, 2001, 69-84.


Cooperative cation and anion coordination by a bifunctional imidophosphorane ligand framework; syntheses and structures of [LiCl{ButNHP)μ-NBut)2PNH(2-py)} 3] and [{ButNP(μ-NBut)2PN(2-py)} Li2·{Li(ButN)2P}]
Bond AD, Doyle EL, Kidd SJ, Woods AD, Wright DS
Chemical Communications, 2001, 8, 777-778.


[(BuNHP)-N-t(mu-NBut)(2)PNH2], a novel building block for neutral and anionic polycyclic main group arrangements
Beswick MA, Elvidge BR, Feeder N, Kidd SJ, Wright DS
CHEM COMMUN, 2001, 4, 379-380.

2000


A Li-10 cage containing the [C6H11P - C(Ph)- N](2-) ion: Umpolung in the oligomerization of a nitrile
Feeder N, Lawson YG, Raithby PR, Rawson JM, Steiner A, Wood JA, Woods AD, Wright DS
ANGEW CHEM INT EDIT, 2000, 22, 4145-4148.


Ligand-directed structural modification of imidotin(II) cubanes: The mixed oxidation state double-cubanes [Sn-7{2-NR}(8)]center dot nTHF (R = pyrimidinyl, 5-methylpyridinyl)
Benevelli F, Doyle EL, Harron EA, Feeder N, Quadrelli EA, Saez D, Wright DS
ANGEW CHEM INT EDIT, 2000, 8, 1501-+.


Aspects of imido-aluminum chemistry.
Tombul M, Wright DS
ABSTR PAP AM CHEM S, 2000, U775-U775.


The paramagnetic, heterometallic manganese cubanes [{E-2(NCy)(4)}(MnCp)(2)] (Cy = C6H11, Cp = C5H5, E = As, Sb)
Bashall A, Beswick MA, Ehlenberg H, Kidd SJ, McPartlin M, Palmer JS, Raithby PR, Rawson JM, Wright DS
CHEM COMMUN, 2000, 9, 749-750.


Synthesis and structure of [Cp2PbCpthf Na]center dot 0.5thf; implications to the control of dimensionality in p block metallocene anion systems (C = C5H5, Cp-thf = {C5H4}CH2C4H7O)
Feeder N, Hopkins AD, Layfield RA, Wright DS
J CHEM SOC DALTON, 2000, 14, 2247-2248.


Synthesis and structure of [(Bu(t)N)P(μ-NBu(t))2P(PCy)Li2·thf]2; an unusual cage compound containing an amido/phosphido functionalised [(Bu(t)N)P(μ-NBu(t))2P(PCy)]2- dianion (Cy = C6H11)
Bashall A, Elvidge BR, Beswick MA, Kidd SJ, McPartlin M, Wright DS
Chemical Communications, 2000, 15, 1439-1440.


Stabilisation of unusual metal co-ordination geometries using an oxo-cubane ligand; syntheses and structures of [{Sn-4((NBu)-Bu-t)(3)O}(3)-LiCl]center dot 3thf and [{Sn-4((NBu)-Bu-t)(3)O}(3)FeCl2]center dot 3thf
Brown C, Mosquera MEG, Palmer JS, Raithby PR, Steiner A, Wright DS
J CHEM SOC DALTON, 2000, 4, 487-490.


Reactions of the spiro monoanion [{(Me2N)Sb(mu-NCy)(2)}(2)Sb](-) with alcohols and thiols (REH; E = O or S); syntheses of nido-[Sb-3(mu-NCy)(3)(mu(3)-NCy)(ER)(2)] anions and the unique antimony(III) imido cubane [(2-NC5H4O)Sb(mu(3)-NCy)](4) (Cy = cyclohexyl)
Bashall A, Beswick MA, Feeder N, Hopkins AD, Kidd SJ, McPartlin M, Raithby PR, Wright DS
J CHEM SOC DALTON, 2000, 12, 1841-1847. DOI: 10.1039/b001322f


Electrophilic ring-opening of [(RP)(n)As](-) anions; a simple route to functionalised neutral phosphines of the type [((BuP)-P-t)((BuRP)-R-t)(2)]
Armstrong DR, Feeder N, Hopkins AD, Mays MJ, Moncrieff D, Wood JA, Woods AD, Wright DS
CHEM COMMUN, 2000, 24, 2483-2484.


A synthetic and structural study of the formation of cyclic [(RP)(n)E](-) anions and Zintl compounds using E(NMe2)(3) (E = As, Sb)
Bashall A, Beswick MA, Choi N, Hopkins AD, Kidd SJ, Lawson YG, Mosquera MEG, McPartlin M, Raithby PR, Wheatley AAEH, Wood JA, Wright DS
J CHEM SOC DALTON, 2000, 4, 479-486.


Association and fragmentation of imidotin(II) complexes containing donor-functionalised peripheries; towards new three-dimensional main group metal ligands
Bashall A, Feeder N, Harron EA, McPartlin M, Mosquera MEG, Saez D, Wright DS
J CHEM SOC DALTON, 2000, 22, 4104-4111. DOI: 10.1039/b005932n


A new highly efficient catalyst system for the coupling of nonactivated and deactivated aryl chlorides with arylboronic acids
Feeder N, Lawson YG, Raithby PR, Rawson JM, Steiner A, Wood JA, Woods AD, Wright DS
Angewandte Chemie - International Edition, 2000, 22, 4153-4155.


Addition of the [((BuP)-Bu-t)(3)As](-) anion to the cyclopentadienyl ring of [(C5H5)M(CO)(3)Cl] (M = Mo, W)
Bashall A, Hopkins AD, Mays MJ, McPartlin M, Wood JA, Woods AD, Wright DS
J CHEM SOC DALTON, 2000, 12, 1825-1826. DOI: 10.1039/b003687k

1999


Synthesis and structure of [{As((NBu)-Bu-t)(3)}(2)Li-6] containing an [As((NBu)-Bu-t)(3)](3-) trianion
Beswick MA, Kidd SJ, Paver MA, Raithby PR, Steiner A, Wright DS
INORG CHEM COMMUN, 1999-12, 12, 612-614.


The first bismuth phosphide complex: [Li(thf)4]+ [{(tBuP)3}2Bi]
Beswick MA, Choi N, Hopkins AD, Lawson YG, McPartlin M, Rothenberger A, Stalke D, Wheatley AEH, Wright DS
Angewandte Chemie - International Edition, 1999, 20, 3053-3055.


The synthesis and structure of [Sn(NMe2)(3)Li]infinity ; an unsolvated polymeric tris(amido) stannate
Beswick MA, Kidd SJ, Raithby PR, Wright DS
INORG CHEM COMMUN, 1999-09, 9, 419-421.


Geometric control of cage architecture; observation of ligand-selective behaviour in the structures of [{As-2(NCy)(4)}(2)M-4] (M = Na, Cu; Cy = C6H11)
Bashall A, Beswick MA, Harron EA, Hopkins AD, Kidd SJ, McPartlin M, Raithby PR, Steiner A, Wright DS
CHEM COMMUN, 1999, 12, 1145-1146.


A metallated primary arsine; synthesis and structure of [PhAsHLi center dot 2thf](infinity)
Beswick MA, Lawson YG, Raithby PR, Wood JA, Wright DS
J CHEM SOC DALTON, 1999, 12, 1921-1922.


A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe2)2}K·pmdeta]2 and [{CyNAs(NMe2)2K}2](∞)
Beswick MA, Bashall A, Hopkins AD, Kidd SJ, Lawson YG, McPartlin M, Raithby PR, Rothenberger A, Stalke D, Wright DS
Chemical Communications, 1999, 8, 739-740.


A leaving group strategy for the selective functionalisation of an imido Sn(II) cubane
Galan B, Mosquera MEG, Palmer JS, Raithby PR, Wright DS
J CHEM SOC DALTON, 1999, 7, 1043-1044.


Structural control in the formation of multidecker sandwich anions of plumbocene: The effects of encapsulating the alkali metal counterions
Beswick MA, Gornitzka H, Karcher T, Mosquera MEG, Palmer JS, Raithby PR, Russell CA, Stalke D, Steiner A, Wright DS
ORGANOMETALLICS, 1999, 7, 1148-1153.


Reactions of organolithium complexes with elemental selenium: insertion producing [PhC CSeLi center dot TMEDA center dot THF] 1 and cyclisation producing [{PhC}(4)Se] 2 (TMEDA = [Me2NCH2](2))
Beswick MA, Harmer CN, Raithby PR, Steiner A, Tombul M, Wright DS
J ORGANOMET CHEM, 1999, 01-Feb, 267-271.


Synthesis and structure of [{As-2(NCy)(4)}(2)Li-4], containing an imido As(III) dianion
Beswick MA, Harron EA, Hopkins D, Raithby PR, Wright DS
J CHEM SOC DALTON, 1999, 2, 107-108.


The hydrogen bonded polymer structures of [{Mn(2-mbiH)2·TMEDA}·A- A](∞) [2-mbiH2 = 2-mercaptobenzimidazole; A-A = TMEDA (Me2NCH2CH2NME2) or DABCO (N{CH2CH2}3N)]
Beswick MA, Mosquera MEG, Palmer JS, Raithby PR, Wright DS
New Journal of Chemistry, 1999, 10, 1033-1039.


Heterometallic complexes of Sn(II)
Mosquera MEG, Palmer JS, Hopkins AD, Wright DS
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1999, 107-116.

1998


Direct synthesis of heterocyclic [(RP)(n)E](-) anions using [E(NMe2)(3)] (E = Sb, As); implications to the mechanism of formation of Zintl compounds
Beswick MA, Choi N, Hopkins AD, McPartlin M, Mosquera MEG, Raithby PR, Rothenberger A, Stalke D, Wheatley AJ, Wright DS
CHEM COMMUN, 1998, 22, 2485-2486.


Mixed alkali metal cages containing the cap-shaped [S(NtBu)(3)](2-) triazasulfite dianion
Ilge D, Wright DS, Stalke D
CHEM-EUR J, 1998-11, 11, 2275-2279.


Synthesis and structure of [{ButP2H}K·pmdeta]2, containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)2NMe]
Beswick MA, Hopkins AD, Kerr LC, Mosquera MEG, Palmer JS, Raithby PR, Rothenberger A, Stalke D, Steiner A, Wheatley AEH, Wright DS
Chemical Communications, 1998, 15, 1527-1528.


Low-temperature synthesis of zintl compounds with a single-source molecular precursor
Beswick MA, Choi N, Harmer CN, Hopkins AD, McPartlin M, Wright DS
Science, 1998, 5382, 1500-1501.


Synthetic applications of p block metal dimethylamido reagents
Beswick MA, Wright DS
COORDIN CHEM REV, 1998-09, 373-406.


Structural direction by the dominant metal
Beswick MA, Mosquera MEG, Wright DS
J CHEM SOC DALTON, 1998, 15, 2437-2443.


Synthesis and structure of [{(BuP)-P-t)(2)H}K center dot pmdeta](2), containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)(2)NMe]
Beswick MA, Hopkins AD, Kerr LC, Mosquera MEG, Palmer JS, Raithby PR, Rothenberger A, Stalke D, Steiner A, Wheatley AEH, Wright DS
CHEM COMMUN, 1998, 15, 1527-1528.


Weakly bonded Lewis base adducts of plumbocene and stannocene: A synthetic and calculational study
Armstrong DR, Beswick MA, Cromhout NL, Harmer CN, Moncrieff D, Russell CA, Raithby PR, Steiner A, Wheatley AEH, Wright DS
ORGANOMETALLICS, 1998, 15, 3176-3181.


Synthesis and structure of the heterobimetallic oxo complex [(thf)(Me2NH)(2)Cl2CrIII](2){ClSnII(mu-O)}(2)
Beswick MA, Choi N, McPartlin M, Mosquera MEG, Palmer JS, Wright DS
CHEM COMMUN, 1998, 13, 1341-1342.


Synthesis and structure of the heterobimetallic ladder complex [{(MesNH)Sn(mu-Nma)}(2)(Li.2THF)(2)] (Mes=2,4,6-Me3C6H2, ma=2-MeOC6H4)
Allan RE, Beswick MA, Feeder N, Kranz M, Mosquera MEG, Raithby PR, Wheatley AEH, Wright DS
INORG CHEM, 1998, 10, 2602-2604.


First structurally characterised lithium hexafluorophosphate complexes with acyclic Lewis bases: ion-separated [Li-2(hmpa)(5)](2+)center dot 2(PF6-) and ion-contacted [(pmdeta)LiPF6](2) [hmpa = (Me2N)(3)PO; pmdeta = MeN(CH2CH2NMe2)(2)]
Armstrong DR, Khandelwal AH, Kerr LC, Peasey S, Raithby PR, Shields GP, Snaith R, Wright DS
CHEM COMMUN, 1998, 9, 1011-1012.


Heterobimetallic (Imido)antimony/Lithium Cages Containing [Sb(NR)(3)](3-) Trianions.
Beswick MA, Choi N, Harmer CN, Hopkins AD, McPartlin M, Paver MA, Raithby PR, Steiner A, Tombul M, Wright DS
Inorg Chem, 1998, 9, 2177-2182.


p-Block metallocenes: The other side of the coin
Beswick MA, Palmer JS, Wright DS
CHEM SOC REV, 1998-05, 3, 225-232.


Co-ordination of heavier alkali metals by polyimido antimony(III) ligands; syntheses and structures of [{Sb2(NC6H11)4}2M 4] (M = Li or Na), Li[{(Me2N)Sb(μ-NC6H11)2} 2Sb]
Bashall A, Beswick MA, Harmer CN, Hopkins AD, McPartlin M, Paver MA, Raithby PR, Wright DS
Journal of the Chemical Society - Dalton Transactions, 1998, 8, 1389-1394.


Aggregation of lithium and mixed thallium(I)-lithium amides through eta(3)- and eta(6)-pi-arene interactions in the solid
Hellmann KW, Galka C, Gade LH, Steiner A, Wright DS, Kottke T, Stalke D
CHEM COMMUN, 1998, 5, 549-550.


Synthesis and structure of [{Sb(NCy)(3)}{Cd[N(SiMe3)(2)]}(3)]center dot[Li{N(SiMe3)(2)}center dot thf](2), containing a bimetallic [SbCd3] cage
Bashall A, Beswick MA, Harmer CN, McPartlin M, Paver MA, Wright DS
J CHEM SOC DALTON, 1998, 4, 517-518.


Synthesis and structure of [{(Bu-t;O)(2)Sb-3(mu-NCy)(3)(mu(3)-NCy)}K.eta(6)-C6H5Me]; a sandwich complex containing a unique Sb-III nido cage anion (Cy=cyclohexyl, C6H11)
Beswick MA, Choi N, Hopkins AD, McPartlin M, Paver MA, Wright DS
CHEM COMMUN, 1998, 2, 261-262.


Reactions of group 14 metallocenes with lithiated primary amines; alternative pathways in the formation of the primary tris(amido)stannate [(MANH)Sn(NHMA)(2)Li.2THF]1 and the cubanes [E(NCy)](4) (E=Sn2, Pb3; MA=(2-MeO)C6H4, Cy=C6H11)
Allan RE, Beswick MA, Davies MK, Raithby PR, Steiner A, Wright DS
J ORGANOMET CHEM, 1998, 01-Feb, 71-76.


Synthesis and structure of [{Sb(NCy)3}{Cd[N(SiMe3)2]} 3]·[Li{N(SiMe3)2}·thf] 2, containing a bimetallic [SbCd3] cage
Bashall A, Beswick MA, Harmer CN, McPartlin M, Paver MA, Wright DS
Journal of the Chemical Society - Dalton Transactions, 1998, 4, 517-518.


Sterically induced cis isomerism in an Sb(III) imido dimer; synthesis, structure and solution dynamics of [(Me2N)Sb(mu-NDipp)](2) (Dipp = 2,6-Pr2iC6H3)
Beswick MA, Harmer CN, Hopkins AD, Paver MA, Raithby PR, Wright DS
POLYHEDRON, 1998, 05-Jun, 745-748.


[(DippNH)(2)Al(mu-NHDipp)(2)Li.thf] and [thf.Li(mu-NHCy)(3)Sn(mu-NHCy)(3)Li.thf].C6H5Me, potential building blocks for heterometallic imido compounds (Dipp=2,6-(Pr2C6H3)-C-i)
Beswick MA, Choi N, Harmer CN, McPartlin M, Mosquera MEG, Raithby PR, Tombul M, Wright DS
CHEM COMMUN, 1998, 13, 1383-1384.


Crystal and molecular structure of (TMEDA)(2)Li2Se4
Worden TAJ, Wright DS, Steiner A
POLYHEDRON, 1998, 23-24, 4011-4014.

1997


Syntheses and structures of [Sn{NR}(2){Sn(mu-NMe2)}(2)]: Model intermediates in the formation of imido group 14 cages and rings [R = 2,6-pr(2)(i)C(6)H(3) (Dipp), 2,4,6-Me3C6H2 (Mes)]
Allan RE, Beswick MA, Coggan GR, Raithby PR, Wheatley AEH, Wright DS
INORG CHEM, 1997, 23, 5202-5205.


Synthesis and structure of [Sn(mit)(6)Cu-4]; a [SnCu4] cage supported by Sn-Cu cluster bonding [mit = (CH)(2)N(Me)C(-S)-N]
Allan RE, Bashall A, Palmer JS, McPartlin M, Mosquera MEG, Rawson JM, Wheatley AEH, Wright DS
CHEM COMMUN, 1997, 20, 1975-1976.


Stoichiometric assembly of [Sb(PCy)(3)](2)Li-6 center dot 6HNMe(2)center dot 2C(6)H(5)Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium
Beswick MA, Goodman JM, Harmer CN, Hopkins AD, Paver MA, Raithby PR, Wheatley AEH, Wright DS
CHEM COMMUN, 1997, 19, 1879-1880.


'Paddle-wheel'' tris(cyclopentadienyl)tin(II) and -lead(II) complexes: Syntheses, structures, and model MO calculations
Armstrong DR, Duer MJ, Davidson MG, Moncrieff D, Russell CA, Stourton C, Steiner A, Stalke D, Wright DS
ORGANOMETALLICS, 1997, 15, 3340-3351.


Synthesis and structure of [Sb{(Pr(i)N)(2)CNHPr(i)}{(Pr(i)N)(2)CNPr(i)}]; A distorted trigonal-bipyramidal antimony(III) complex with a helical hydrogen-bond network
Bailey PJ, Gould RO, Harmer CN, Pace S, Steiner A, Wright DS
CHEM COMMUN, 1997, 13, 1161-1162.


Nucleophilic substitution vs. acid-base reactions of [Mn{N(SiMe3)2}2]·2thf; syntheses and structures of
Beswick MA, Harmer CN, Raithby PR, Steiner A, Verhorevoort KL, Wright DS
Journal of the Chemical Society - Dalton Transactions, 1997, 12, 2029-2032.


Assembly of Mixed-Metal Cages Using Polyimido Antimony(III) Anions. Syntheses and Structures of [Sb(3)(NCy)(4)(HNCy)(2)]K.2(toluene), [Sb(2)(NCy)(4)](2)M(4) (M = Cu, Ag), and [Sb(NCy)(3)](2)Pb(3) (Cy = Cyclohexyl, C(6)H(11)).
Beswick MA, Cromhout NL, Harmer CN, Paver MA, Raithby PR, Rennie MA, Steiner A, Wright DS
Inorg Chem, 1997, 9, 1740-1744.


A tetrakis(imido) phosphate anion isoelectronic with PO43-
Raithby PR, Russell CA, Steiner A, Wright DS
ANGEW CHEM INT EDIT, 1997, 6, 649-650.


Metal selection of ligand functionality in [(mes)(2)P(-O)(2)Li center dot 2thf](2) and [{(Me(3)Si)(2)N}Cd{(mes)(2)P-O}Li-2 center dot 2thf](mes equals C(6)H(2)Me(3)-2,4,6)
Beswick MA, Cromhout NL, Harmer CN, Palmer JS, Raithby PR, Steiner A, Verhorevoort KL, Wright DS
CHEM COMMUN, 1997, 6, 583-584.


Synthesis and structure of [Pb(2-Py)(3)Li center dot THF], containing a low-valent group 14 tris(pyridyl) ligand (2-Py equals 2-pyridyl)
Beswick MA, Davies MK, Raithby PR, Steiner A, Wright DS
ORGANOMETALLICS, 1997, 6, 1109-1110.


beta-Trans-[N-4{P(Ph)(C6H11N)}(4)](4-); A tetraanionic ligand system exhibiting two separated tetradentate coordination sites of concave-shaped cavities
Steiner A, Wright DS
CHEM COMMUN, 1997, 3, 283-284.


Solvent directed aggregation of a metallocene; structures of {[Pb(η-C5H5)2]3·C 6H5Me}∞ and [Pb(η-C5H5)2]6
Beswick MA, Lopez-Casideo C, Paver MA, Raithby PR, Russell CA, Steiner A, Wright DS
Chemical Communications, 1997, 1, 109-110.


Structured assembly of heterometallic arrays
Beswick MA, Davies MK, Harmer CN, Hopkins AD, Mosquera MEG, Palmer JS, Paver MA, Raithby PR, Wright DS
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1997, 103-112.


Metal selection of ligand functionality in [(mes)2P(-..O)2Li·2thf]2 and [{(Me3Si)2N}Cd{(mes)2P-..O} 2Li·2thf] (mes = C6H2Me3-2,4,6)
Beswick MA, Cromhout NL, Harmer CN, Palmer JS, Raithby PR, Steiner A, Verhorevoort KL, Wright DS
Chemical Communications, 1997, 6, 583-584.

1996


One-pot synthesis of a novel tridentate tin(IV) ligand; Syntheses and structures of [Bu(n)Sn(NC5H4-C,N)(3)MBr] (M=Li, Cu)
Beswick MA, Belle CJ, Davies MK, Halcrow MA, Raithby PR, Steiner A, Wright DS
CHEM COMMUN, 1996, 23, 2619-2620.


Build-up of an Al4P6Li4 cage from an Al4N4 cubane: Synthesis and structure of [Li(OC4H8)](4)[{(AlMe)[mu-P(C6H11)]}(2){mu-P(C6H11)}](2)center dot C(6)H(5)Me
Allan RE, Beswick MA, Raithby PR, Steiner A, Wright DS
J CHEM SOC DALTON, 1996, 22, 4153-4154.


Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [(Ph(3)P)(2)CuL(2)Li(thf)(2)]center dot thf and tetrameric [{CuL(PPh(3))}(4)] (L=1,3-benzoxazoline-2-thionate, thf equals tetrahydrofuran)
Beswick MA, Brasse C, Halcrow MA, Raithby PR, Russell CA, Steiner A, Snaith R, Wright DS
J CHEM SOC DALTON, 1996, 19, 3793-3797.


Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C5H5)2Pb·tmeda] and [(η -C5H5)2Pb·4,4′-Me2 bipy] (tmeda = Me2NCH2CH2NMe2, 4,4′-Me2bipy = 4,4′-dimethylbipyridine)
Beswick MA, Cromhout NL, Harmer CN, Raithby PR, Russell CA, Smith JSB, Steiner A, Wright DS
Chemical Communications, 1996, 16, 1977-1978.


[Sb-12{(2-MeO)C6H4N}(18)]center dot 6THF; A twenty-four membered imidoantimony(III) metallacycle
Beswick MA, Davies MK, Paver MA, Raithby PR, Steiner A, Wright DS
ANGEW CHEM INT EDIT, 1996, 13-14, 1508-1510.


Fragmentation of an imido tin(II) cubane; Syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions
Allan RE, Beswick MA, Cromhout NL, Paver MA, Raithby PR, Steiner A, Trevithick M, Wright DS
CHEM COMMUN, 1996, 13, 1501-1502.


Synthesis and structure of [Bi-2(N(t)Bu)(4)]Li-2(2)center dot 2THF; A bimetallic cubane fragment containing a [Bi-2(N(t)Bu)(4)](2-) anion
Edwards AJ, Beswick MA, Galsworthy JR, Paver MA, Raithby PR, Rennie MA, Russell CA, Verhorevoort KL, Wright DS
INORG CHIM ACTA, 1996, 1, 9-14.


Synthesis and structure of [{(Me(3)Si)(2)N}(2)Cd{(PhN)(3)C}Li-2 center dot 3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments
Bailey PJ, Mitchell LA, Raithby PR, Rennie MA, Verhorevoort K, Wright DS
CHEM COMMUN, 1996, 11, 1351-1352.


Selenium insertion into a cadmium-carbon bond; Synthesis and structural characterisation of the loosely linked dimer [{Cd(SeC CPh)(2)(tmen)}(2)] (tmen=Me(2)NCH(2)CH(2)NMe(2))
Beswick MA, Raithby PR, Steiner A, Vallat JC, Verhorevoort KL, Wright DS
J CHEM SOC DALTON, 1996, 10, 2183-2184.


Structure and reactivity of [{Te(NMe(2))(2)}(infinity)]; Application to the preparation of metalloorganic tellurium(II) compounds
Alan RE, Gornitzka H, Karcher J, Paver M, Rennie MA, Russell CA, Raithby PR, Stalke D, Steiner A, Wright DS
J CHEM SOC DALTON, 1996, 8, 1727-1730.


Hexalithiated hexakis(cyclohexylamino)-cyclotriphosphazene; A (Li+)(12) cage containing puckered [NP(NCy)(2)](6-)(3) ions
Steiner A, Wright DS
ANGEW CHEM INT EDIT, 1996, 6, 636-637.


Synthesis and structure of the bis(imido)gold complex [Au-5(I)(NtBu)(2)(PPh(3))(4)](+)Cl(-)center dot 2C(6)H(5)CH(3); A higher homologue of the organotris(triphenylphosphaneaurio)ammonium ions
Allan RE, Beswick MA, Paver MA, Raithby PR, Steiner A, Wright DS
ANGEW CHEM INT EDIT, 1996, 2, 208-209.


Structural variation in silver acetylide complexes: Syntheses and X-ray structure determinations of [Ph(3)PAgC CPh](4)center dot 3.5THF and [Me(3)PAgC CSiMe(3)](infinity)
Brasse C, Raithby PR, Rennie MA, Russell CA, Steiner A, Wright DS
ORGANOMETALLICS, 1996, 2, 639-644.


A halide-free route to Groups 12 and 13 organometallic and metalloorganic complexes
Edwards AJ, Fallaize A, Raithby PR, Rennie MA, Steiner A, Verhorevoort KL, Wright DS
J CHEM SOC DALTON, 1996, 1, 133-137.

1995


SYNTHESIS AND STRUCTURE OF THE DIMERIC ORGANO-ANTIMONY(V) IMIDO COMPLEX [PH(3)SB(MU-NCH(2)CH(2)PH)](2)
EDWARDS AJ, PAVER MA, PEARSON P, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
J ORGANOMET CHEM, 1995, 1, C29-C31.


MIXED ORGANOZINC-DIORGANOPHOSPHIDE COMPLEX CONTAINING PROTIC PHOSPHINE-LIGANDS BONDED TO ZINC
DAVIDSON MG, EDWARDS AJ, PAVER MA, RAITHBY PR, RUSSELL CA, STEINER A, VERHOREVOORT KL, WRIGHT DS
J CHEM SOC CHEM COMM, 1995, 19, 1989-1990.


LIGAND TRANSFER FROM A TRIS(IMINO)STANNATE ANION - SYNTHESES AND STRUCTURES OF [(CU[MU-N=C(BU(T))PH])(4)]CENTER-DOT-THF (THF=TETRAHYDROFURAN) AND [(CU[MU-N=C(BU(T))PH])(4)(PPH(3))(2)]CENTER-DOT-6THF
DAVIES MK, RAITHBY PR, RENNIE MA, STEINER A, WRIGHT DS
J CHEM SOC DALTON, 1995, 16, 2707-2709.


STRUCTURE AND BONDING IN ORGANOMETALLIC ANIONS OF HEAVY GROUP-14 AND GROUP-15 ELEMENTS
PAVER MA, RUSSELL CA, WRIGHT DS
ANGEW CHEM INT EDIT, 1995, 15, 1545-1554.


FACILE SYNTHESIS OF SN4N4 CUBANES - SYNTHESES AND STRUCTURES OF [SN(NC6H11)](4) AND [SN(2-NCH2C5H4N)](4)
ALLAN RE, BESWICK MA, EDWARDS AJ, PAVER MA, RENNIE MA, RAITHBY PR, WRIGHT DS
J CHEM SOC DALTON, 1995, 12, 1991-1994.


SYNTHESIS AND STRUCTURE OF THE MIXED ANION SANDWICH COMPLEX ([(C5H5)(9)PB-4]-[(C5H5)(5)PB-2](-)[LI(12-CROWN-4)(2)](+)(2))
DUER MJ, PAGE NA, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, STOURTON C, STEINER A, WRIGHT DS
J CHEM SOC CHEM COMM, 1995, 11, 1141-1142.


STEP-WISE NUCLEOPHILIC-SUBSTITUTION OF BIS(CYCLOPENTADIENYL)TIN(II) - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(SN(ETA(3)-C5H5)[MU-N=C(NME(2))(2)])(2)] AND [(SN[S(CH2)(3)SC(R)]-[MU-N=C(NME(2))(2)])(2)] (R=H OR SIME(3))
EDWARDS AJ, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
J CHEM SOC DALTON, 1995, 10, 1587-1591.


SYNTHESES AND STRUCTURAL STUDIES OF 2 ADDUCTS OF CADMOCENE, [CDCP(2).TMEDA] AND [CDCP(2).PMDETA] (TMEDA=ME(2)NCH(2)CH(2)NME(2), PMDETA=(ME(2)NCH(2)CH(2))(2)NME)
BARR D, EDWARDS AJ, RAITHBY PR, RENNIE MA, VERHOREVOORT KL, WRIGHT DS
J ORGANOMET CHEM, 1995, 01-Feb, 175-179.


CAGE EXPANSION OF [((CYNLI)(3)SB)(2)] - SYNTHESIS AND STRUCTURE OF THE TRIMETALLIC COMPLEX [((CYNLI)(3)SB)(2)(TBUOK)(3)-CENTER-DOT-X-C6H5CH3]
BARR D, EDWARDS AJ, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
ANGEW CHEM INT EDIT, 1995, 9, 1012-1013.


THE NEXT HOMOLOG OF THE BIS(CYCLOPENTADIENYL)THALLATE ANION - SYNTHESIS AND X-RAY STRUCTURE DETERMINATION OF [(ETA(5)-CSH5)TL(MU-C5H5)TL(ETA(5)-C5H(5))]-[LI(12-CROWN-4)(2)](+)THF
ARMSTRONG DR, EDWARDS AJ, MONCRIEFF D, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
J CHEM SOC CHEM COMM, 1995, 9, 927-928.


Synthesis and structure of [Li(thf)(4)](2)(Ph(2)P)(10)Cd-4] containing a dianion with a Cd4P10 adamantanoid core
Beswick MA, Raithby PR, Russell CA, Steiner A, Verhorevoort KL, Ward GN, Wright DS
ANGEW CHEM INT EDIT, 1995, 23-24, 2662-2664.

1994


PREPARATION OF COPPER ORGANOMETALLICS VIA NUCLEOPHILIC-SUBSTITUTION OF CPCUPPH(3) - SYNTHESES AND X-RAY STRUCTURE DETERMINATIONS OF [LI(THF)(4)](+)[(FLUORENYL)(2)CUPPH(3)](-) AND [CY(3)PCU(MU-C-C(T)BU)(2)CU(PPH(3))(2)] (THF=TETRAHYDROFURAN, FLUORENYL=C13H9)
EDWARDS AJ, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
ORGANOMETALLICS, 1994-12, 12, 4967-4972.


INTRAMOLECULAR VERSUS INTERMOLECULAR BONDING IN AMIDOANTIMONY DIMERS - SYNTHESES AND STRUCTURES OF (SB(NME(2))[MU-N(MPY)])(2) (MPY=4-METHYLPYRIDIN-2 YL) AND [SB(NME(2))(MU-N[C6H2(OME)(3)-3,4,5])](2)
EDWARDS AJ, PAVER MA, RENNIE MA, RAITHBY PR, RUSSELL CA, WRIGHT DS
J CHEM SOC DALTON, 1994, 20, 2963-2966.


[(SB-2(NCY)(4))CU-2(4)] - A MIXED-METAL ANTIMONY(III)/COPPER(I) COMPLEX CONTAINING A CU-4 SQUARE PLANE
BARR D, EDWARDS AJ, PULLEN S, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
ANGEW CHEM INT EDIT, 1994, 18, 1875-1876.


A NEW HALIDE-FREE ROUTE TO METALLOORGANIC CADMIUM COMPLEXES - SYNTHESES AND STRUCTURAL CHARACTERIZATIONS OF [CD(PHCC)(2)(TMEDA)] AND [CD(C12H8N)(4)](2-).2LI(THF)(4)+ (TMEDA=ME(2)NCH(2)CH(2)NME(2))
BARR D, EDWARDS AJ, RAITHBY PR, RENNIE MA, VERHOREVOORT K, WRIGHT DS
J CHEM SOC CHEM COMM, 1994, 14, 1627-1628.


SYNTHESIS AND STRUCTURE OF [SB2LI2(N(C6H11))4]2 - A CAGE COMPLEX CONTAINING A CORE OF 2 INTERLOCKED BROKEN CUBES
ALTON RA, BARR D, EDWARDS AJ, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
J CHEM SOC CHEM COMM, 1994, 12, 1481-1482.


A NEW METHOD FOR THE SYNTHESIS OF HETEROMETALLIC COMPLEXES - SYNTHESES AND STRUCTURES OF [(PHCH(2)CH(2)NLI)(3)SB(THF)](2) AND [SB-3(CYN)(4)(NME(2))(2)]LI
EDWARDS AJ, PAVER MA, RAITHBY PR, RENNIE MA, RUSSELL CA, WRIGHT DS
ANGEW CHEM INT EDIT, 1994, 12, 1277-1279.


2 TRIS(IMINO)TIN(II) AND TRIS(IMINO)LEAD(II) CAGE COMPLEXES - SYNTHESES AND STRUCTURES OF E[MU-N=C((T)BU)PH]3LI-CENTER-DOT-THF (E=SN, PB)
EDWARDS AJ, PAVER MA, RAITHBY PR, RUSSELL CA, STEINER A, STALKE D, WRIGHT DS
INORG CHEM, 1994, 11, 2370-2375.


DIMERIC ANTIMONY COMPLEXES CAPTURING DIMETHYLAMINE AS A NEUTRAL DONOR - SYNTHESES AND STRUCTURAL CHARACTERIZATION OF [SBCL2(NHME2)(MU-OET)]2 AND [SBCL(NHME2)(MU-NBU-T)]2
EDWARDS AJ, LEADBEATER NE, PAVER MA, RAITHBY PR, RUSSELL CA, WRIGHT DS
J CHEM SOC DALTON, 1994, 9, 1479-1482.


ETA(3) AND ETA(6) BRIDGING CATIONS IN THE N,N,N',N'',N''-PENTAMETHYLDIETHYLENETRIAMINE-SOLVATED COMPLEXES OF BENZYLPOTASSIUM AND BENZYLRUBIDIUM - AN X-RAY, NMR, AND MO STUDY
HOFFMANN D, BAUER W, HAMPEL F, HOMMES NJRV, SCHLEYER PV, OTTO P, PIEPER U, STALKE D, WRIGHT DS, SNAITH R
J AM CHEM SOC, 1994, 2, 528-536.


Two tris(imino)tin(II) and -lead(II) cage complexes. Syntheses and structures of E[μ-N=C(tBu)Ph]3Li·THF (E = Sn, Pb)
Edwards AJ, Paver MA, Raithby PR, Russell CA, Steiner A, Stalke D, Wright DS
Inorganic Chemistry, 1994, 11, 2370-2375.

1993


THE BIS(CYCLOPENTADIENYL)THALLATE(I) ANION ISOELECTRONIC WITH STANNOCENE
ARMSTRONG DR, HERBSTIRMER R, KUHN A, MONCRIEFF D, PAVER MA, RUSSELL CA, STALKE D, STEINER A, WRIGHT DS
ANGEW CHEM INT EDIT, 1993-12, 12, 1774-1776.


THE BROKEN CUBE POLYMER STRUCTURE OF (LIBR-CENTER-DOT-THF)(INFINITY) (THF = TETRAHYDROFURAN)
EDWARDS AJ, PAVER MA, RAITHBY PR, RUSSELL CA, WRIGHT DS
J CHEM SOC DALTON, 1993, 21, 3265-3266.


A TRIMERIC, CHAIR-SHAPED ZINC DIALKYLPHOSPHINE COMPLEX - SYNTHESIS AND STRUCTURE OF ([ZN(ET)(MU-PCY2)]3.THF).2THF [CY = CYCLOHEXYL (C6H11)]
EDWARDS AJ, PAVER MA, RAITHBY PR, RUSSELL CA, WRIGHT DS
ORGANOMETALLICS, 1993-11, 11, 4687-4690.


A MODEL INTERMEDIATE FOR THE NUCLEOPHILIC-SUBSTITUTION OF (CP)2SN - SYNTHESIS AND STRUCTURE OF (CP)(ME3SI)2NSN(MU-CP)LI.PMDETA [CP = C5H5, PMDETA = (ME2NCH2CH2)2NME]
PAVER MA, RUSSELL CA, STALKE D, WRIGHT DS
J CHEM SOC CHEM COMM, 1993, 17, 1349-1350.


STRUCTURE OF BIS(PENTAMETHYLDIETHYLENETRIAMINE)DISODIUM HEXASULFIDE
BESSER S, HERBSTIRMER R, STALKE D, BROOKER AT, SNAITH R, WRIGHT DS
ACTA CRYSTALLOGR C, 1993, 1482-1483.


SYNTHESIS AND CRYSTAL-STRUCTURE OF SB(N=CPH2)3
EDWARDS AJ, PAVER MA, RAITHBY PR, RUSSELL CA, WRIGHT DS
J CHEM SOC DALTON, 1993, 14, 2257-2258.


THE 1ST IMINO-LEAD COMPLEX - SYNTHESIS AND X-RAY CHARACTERIZATION OF PB[MU-N=C(BU(T))PH](3)LITHF (THF = TETRAHYDROFURAN)
EDWARDS AJ, PAVER MA, RAITHBY PR, RUSSELL CA, WRIGHT DS
J CHEM SOC CHEM COMM, 1993, 13, 1086-1088.


STRUCTURE OF THE LITHIUM THIOCYANATE-TETRAMETHYLPROPYLENEDIAMINE COMPLEX DIMER, [LINCS.ME2N(CH2)3NME2]2, WITH ASYMMETRIC NCS-BRIDGE BONDING - A NEW BONDING MODE FOR THE THIOCYANATE LIGAND
ARMSTRONG DR, KHANDELWAL AH, RAITHBY PR, SNAITH R, STALKE D, WRIGHT DS
INORG CHEM, 1993, 10, 2132-2136.


GENERAL EQUATIONS FOR DETERMINING SPECIES INVOLVED IN SOLUTION EQUILIBRIA AND EQUILIBRIUM-CONSTANTS FROM SOLUTION MOLECULAR MASS MEASUREMENTS
DAVIDSON MG, SNAITH R, STALKE D, WRIGHT DS
J ORG CHEM, 1993, 10, 2810-2816.


2 TRIORGANOSTANNATE COMPLEXES SYNTHESIZED FROM BIS(CYCLOPENTADIENYL)TIN(II) - STRUCTURAL VARIATION BETWEEN [MG(THF)6]2+2[SN(ETA-3-C5H5)3]- AND [LI(THF)4]+[SN(C13H9)3]- (THF = TETRAHYDROFURAN, C13H9 = FLUORENYL)
EDWARDS AJ, PAVER MA, RAITHBY PR, RUSSELL CA, STALKE D, STEINER A, WRIGHT DS
J CHEM SOC DALTON, 1993, 9, 1465-1466.


NUCLEOPHILIC-SUBSTITUTION OF BIS(CYCLOPENTADIENYL)-TIN(II) - SYNTHESIS, STRUCTURE, AND SOLUTION DYNAMICS OF TRANS-[(ETA-3-CP)SN(MU-2-N=C(NME2)2)]2
STALKE D, PAVER MA, WRIGHT DS
ANGEW CHEM INT EDIT, 1993-03, 3, 428-429.


A THIOURACIL CA-2+ COMPLEX CONTAINING 2 TAUTOMERIC FORMS OF THE THIOURACILYL ANION - SYNTHESIS AND CRYSTAL-STRUCTURE OF [(THIOURACILYL)2CA.2DMSO.H2O]2
BANBURY FA, DAVIDSON MG, EDWARDS AJ, SOLERA MIL, RAITHBY PR, SNAITH R, STALKE D, WRIGHT DS
INORG CHIM ACTA, 1993, 1, 93-95.


METALATIONS OF 1-AMINONAPHTHALENE WITH ALME3 AND WITH ZNET2 - SYNTHESES AND CRYSTAL-STRUCTURES OF CYCLOBUTANE-LIKE [ME2AL(N(H)NAPHTHYL)]2 AND CYCLOHEXANE-LIKE [ET2N(N(H)NAPHTHYL).THF]3
DAVIDSON MG, ELILIO D, LESS SL, MARTIN A, RAITHBY PR, SNAITH R, WRIGHT DS
ORGANOMETALLICS, 1993-01, 1, 1-3.

1992


THE OBSERVATION OF A PB-LI BOND - SYNTHESIS, STRUCTURE AND MODEL MOLECULAR-ORBITAL (MO) CALCULATIONS ON THE MONOMERIC PH3PB-LI.(PMDETA) COMPLEX [PMDETA=(ME2NCH2CH2)2NME]
ARMSTRONG DR, DAVIDSON MG, MONCRIEFF D, STALKE D, WRIGHT DS
J CHEM SOC CHEM COMM, 1992, 19, 1413-1415.


[(ETA-5-CP)2SN(MU-ETA-5-CP)NA.PMDETA], A COMPOUND WITH A TRIGONAL-PLANAR PADDLE WHEEL TRIORGANOSTANNATE ION
DAVIDSON MG, STALKE D, WRIGHT DS
ANGEW CHEM INT EDIT, 1992-09, 9, 1226-1227.


METAL-MEDIATED CONVERSION OF A 5-AMINOTHIATRIAZOLE INTO A 5-MERCAPTOTETRAZOLYL LIGAND BY REACTION WITH A SOLID METAL HYDROXIDE - SYNTHESIS AND CRYSTAL-STRUCTURE OF [CYCLO-NAPHTHYLN-BULLET-N=N-BULLET-N-RADICAL-ANIONC(RADICAL-ANIONS)]2BA-BULLET-3HMPA
BANBURY FA, DAVIDSON MG, MARTIN A, RAITHBY PR, SNAITH R, VERHOREVOORT KL, WRIGHT DS
J CHEM SOC CHEM COMM, 1992, 16, 1152-1154.


THE 1ST CALCIUM-MERCURY COCOMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE
DAVIDSON MG, LLEWELLYN SC, SOLERA MIL, RAITHBY PR, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1992, 7, 573-575.


ISOLATION, STRUCTURE AND MO CALCULATIONAL INVESTIGATIONS OF A HIGHLY STABLE, HYDROGEN-BONDED PRIMARY AMINE PHOSPHINE OXIDE ADDUCT, 2-AMINOBENZOTHIAZOLE HMPA, C6H4SC(=N)NH2.O=P(NME2)3 - A POSSIBLE MODEL TO EXPLAIN THE CARCINOGENICITY OF HMPA (HMPA = HEXAMETHYLPHOSPHORAMIDE)
ARMSTRONG DR, BENNETT S, DAVIDSON MG, SNAITH R, STALKE D, WRIGHT DS
J CHEM SOC CHEM COMM, 1992, 3, 262-264.

1991


THE REACTION OF PTCL2 WITH AN N,S,O-COORDINATED CALCIUM COMPLEX - SYNTHESIS AND STRUCTURE OF A COMPLEXED CAPT ANION
DAVIDSON MG, RAITHBY PR, SNAITH R, STALKE D, WRIGHT DS
ANGEW CHEM INT EDIT, 1991-12, 12, 1648-1650.


DILITHIATION OF A PRIMARY AMINE - SYNTHESIS AND STRUCTURE OF [(ALPHA-NAPHTHYL-NLI2)10(ET2O)6].ET2O, A PARAMAGNETIC LI20 AGGREGATE
ARMSTRONG DR, BARR D, CLEGG W, DRAKE SR, SINGER RJ, SNAITH R, STALKE D, WRIGHT DS
ANGEW CHEM INT EDIT, 1991-12, 12, 1707-1709.


OBSERVATION OF A DIRECT SN-LI BOND - THE CRYSTAL AND MOLECULAR-STRUCTURE OF MONOMERIC [PH3SNLI.PMDETA] AND THE DETECTION OF SN-119, SN-117-LI-7 NMR COUPLING IN SOLUTION
REED D, STALKE D, WRIGHT DS
ANGEW CHEM INT EDIT, 1991-11, 11, 1459-1460.


MIXED-ANION AGGREGATES OF METALATED ORGANICS - PREPARATION AND STRUCTURE OF THE MIXED-ANION TETRAMER (PHO-LI+.HMPA)3(MU-3-HMPA.LI+)NCS-
RAITHBY PR, REED D, SNAITH R, WRIGHT DS
ANGEW CHEM INT EDIT, 1991-08, 8, 1011-1013.


THE STABILIZATION OF WATER AS A LIGAND IN LITHIATED ORGANIC-COMPOUNDS - INTRAMOLECULAR AND INTERMOLECULAR HYDROGEN-BONDING IN THE STRUCTURES OF THE AQUO COMPLEXES [C6H4OC(=S)=NLI-HMPA-H2O]2 AND [C6H4OC(=S)=NLI-HMPA]2-H2O
ARMSTRONG DR, BARR D, RAITHBY PR, SNAITH R, WRIGHT DS, SCHLEYER PV
INORG CHIM ACTA, 1991, 2, 163-167.


ALKALINE-EARTH METAL-COMPLEXES CONTAINING DEPROTONATED ORGANIC-ACIDS AND WATER - PREPARATION, STRUCTURES AND A NEW SYNTHETIC STRATEGY
MIKULCIK P, RAITHBY PR, SNAITH R, WRIGHT DS
ANGEW CHEM INT EDIT, 1991-04, 4, 428-430.


LITHIATIONS OF MERCAPTOAMINES CONTAINING =NC(=S)NH-,-NHC(=S)S-AND-NHC(=S)NH-UNITS - SYNTHESES, CRYSTAL-STRUCTURES AND MODEL MOLECULAR-ORBITAL CALCULATIONS
ARMSTRONG DR, MULVEY RE, BARR D, PORTER RW, RAITHBY PR, SIMPSON TRE, SNAITH R, WRIGHT DS, GREGORY K, MIKULCIK P
J CHEM SOC DALTON, 1991, 765-776.


AGGREGATION OF AZA CROWN ETHERS BY METALATION - SYNTHESIS AND CRYSTAL-STRUCTURE OF 1-LITHIO-1,7-DIAZA[12]CROWN-4 - THE 1ST LITHIATED CROWN-ETHER
BARR D, BERRISFORD DJ, MENDEZ L, SLAWIN AMZ, SNAITH R, STODDART JF, WILLIAMS DJ, WRIGHT DS
ANGEW CHEM INT EDIT, 1991-01, 1, 82-84.

1990


THE 1ST LITHIATED ORGANIC-COMPOUND CONTAINING WATER AS A LIGAND - SYNTHESIS AND CRYSTAL-STRUCTURE OF 2-MERCAPTOBENZOXAZOLYL(TETRAMETHYLETHYLENEDIAMINE)LITHIUM MONOHYDRATE, C6H4OC(=S)=NLI(TMEDA)H2O, A MODEL ACID-BASE INTERMEDIATE
BARR D, RAITHBY PR, SCHLEYER PV, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1990, 8, 643-645.


[PHLINCH2CH2NLIPH].3HMPA, A MONOMERIC DILITHIUMETHYLENEDIAMIDE COMPLEX WITH N2LI2 DOUBLE BRIDGING - SYNTHESIS, CRYSTAL-STRUCTURE, AND MODEL MO CALCULATIONS
ARMSTRONG DR, BARR D, BROOKER AT, CLEGG W, GREGORY K, HODGSON SM, SNAITH R, WRIGHT DS
ANGEW CHEM INT EDIT, 1990-04, 4, 410-411.


THE AMMONIUM SALT ROUTE TO OLIGOMERIC LANTHANUM SALT COMPLEXES - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF LA(NCS)3.4HMPA
BARR D, BROOKER AT, DOYLE MJ, DRAKE SR, RAITHBY PR, SNAITH R, WRIGHT DS
ANGEW CHEM INT EDIT, 1990-03, 3, 285-287.


UNUSUAL ROUTES TO COMPLEXES OF BINARY ALKALI-METAL NONMETAL COMPOUNDS - PREPARATIONS AND CRYSTAL AND SOLUTION STRUCTURES OF LI2S6.(TMEDA)2 (TMEDA = TETRAMETHYLETHYLENEDIAMINE), AND SYNTHETIC EXTENSIONS OF THE ROUTES
BANISTER AJ, BARR D, BROOKER AT, CLEGG W, CUNNINGTON MJ, DOYLE MJ, DRAKE SR, GILL WR, MANNING K, RAITHBY PR, SNAITH R, WADE K, WRIGHT DS
J CHEM SOC CHEM COMM, 1990, 2, 105-107.

1989


[H2C(CH2)5NLI]6, THE 1ST CYCLIZED LITHIUM AMIDE LADDER - SYNTHESIS AND STRUCTURE OF HEXAMETHYLENEIMIDOLITHIUM
BARR D, CLEGG W, HODGSON SM, LAMMING GR, MULVEY RE, SCOTT AJ, SNAITH R, WRIGHT DS
ANGEW CHEM INT EDIT, 1989-09, 9, 1241-1243.


2 MONOMERIC, OCTAHEDRAL COMPLEXES OF ALKALINE-EARTH METAL-SALTS - SYNTHESES, PHYSICAL CHARACTERISTICS, AND CRYSTAL-STRUCTURES OF SRI2.4HMPA AND SR(NCS)2.4HMPA [HMPA=O-P(NME2)3]
BARR D, BROOKER AT, DOYLE MJ, DRAKE SR, RAITHBY PR, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1989, 14, 893-895.


A K3-CONTAINING TRIGONAL-BIPYRAMIDAL CLUSTER - SYNTHESIS OF (KSCN)3.5HMPA BY REACTION OF SOLID NH4SCN WITH SOLID K OR KH IN TOLUENE HMPA AND ITS CRYSTAL-STRUCTURE REVEALING A TRIANGLE OF 3 K+ IONS LINKED BY 3 EQUATORIAL MU-2-HMPA LIGANDS AND BICAPPED BY 2 MU-3-HMPA LIGANDS
BARR D, DOYLE MJ, DRAKE SR, RAITHBY PR, SNAITH R, WRIGHT DS
INORG CHEM, 1989, 10, 1767-1768.


A UNIQUE LITHIUM HALIDE COMPLEX, [(LIBR)2.3HMPA.TOLUENE] - SYNTHESIS FROM REACTION OF SOLID NH4BR WITH BUNLI IN HMPA (HEXAMETHYLPHOSPHORAMIDE) TOLUENE MEDIA, CRYSTAL-STRUCTURE SHOWING 2 LI-BR UNITS LINKED BY 3 MU-2-HMPA LIGANDS, AND DETECTION OF LI-7... P-31 COUPLING IN SOLUTIONS OF THE COMPLEXH
BARR D, DOYLE MJ, MULVEY RE, RAITHBY PR, REED D, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1989, 5, 318-319.


DILITHIATION OF N,N'-DIPHENYLTHIOUREA, PHNHC(=S)NHPH, IN HMPA - THE UNEXPECTED STRUCTURE OF THE PRODUCT, [PHNLIC(=NPH)SLI.2HMPA]2, AND SUPPORTING ABINITIO MO CALCULATIONS ON MODEL SYSTEMS
ARMSTRONG DR, MULVEY RE, BARR D, SNAITH R, WRIGHT DS, CLEGG W, HODGSON SM
J ORGANOMET CHEM, 1989, 01-Feb, C1-C4.


REACTION OF SOLID SODIUM HYDRIDE WITH SOLID AMMONIUM THIOCYANATE IN HMPA-TOLUENE - AN ESR SPECTROSCOPIC INVESTIGATION AND CRYSTAL-STRUCTURES OF THE 2 PRODUCTS OF THE REACTION, [(NANCS.HMPA)2] INFINITY AND (NANCS.2HMPA)2
BARR D, DOYLE MJ, DRAKE SR, RAITHBY PR, SNAITH R, WRIGHT DS
POLYHEDRON, 1989, 2, 215-218.


Ladder structures in lithium amide chemistry: Syntheses and solid-state and solution structures of donor-deficient lithium pyrrolidide complexes, {[H2C(CH2)3NLi]3·PMDETA} 2 and {[H2C(CH2)3NLi]2·TMEDA} 2, and ab initio MO calculations probing ring...
Armstrong DR, Barr D, Clegg W, Hodgson SM, Mulvey RE, Reed D, Snaith R, Wright DS
Journal of the American Chemical Society, 1989, 13, 4719-4727.

1988


EVIDENCE FOR A RADICAL-FORMING PROCESS DURING THE REACTION OF SOLID NH4SCN WITH NORMAL-BUTYL-LITHIUM AND HEXAMETHYLPHOSPHORAMIDE (HMPA) IN TOLUENE - CRYSTAL-STRUCTURE OF THE PRODUCT, (LINCS.2HMPA)2
BARR D, DOYLE MJ, DRAKE SR, RAITHBY PR, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1988, 21, 1415-1417.


A LI-8 CLUSTER OF 3 EDGE-CONNECTED LI-4 TETRAHEDRA HELD BY LI-N, LI=C, AND LI=LI INTERACTIONS - CRYSTAL-STRUCTURE OF (ORTHO-LIC6H4CH2.NLI.CH2CH2NME2)4 AND DETECTION OF METAL=METAL COUPLING WITHIN IT BY LI-7 COSY NMR-SPECTROSCOPY
BARR D, CLEGG W, HODGSON SM, MULVEY RE, REED D, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1988, 5, 367-369.


SYNTHESIS, AND CRYSTAL AND SOLUTION STRUCTURES OF THE 1-1 TMEDA COMPLEX OF LITHIUM THIOCYANATE, (LISCN.TMEDA)N [TMEDA = ME2N(CH2)2NME2] - A POLYMERIC SOLID WITH LI+ IONS LINKED BY BIFUNCTIONAL LINEAR SCN- LIGANDS
BARR D, DOYLE MJ, MULVEY RE, RAITHBY PR, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1988, 2, 145-147.

1987


REACTIONS OF AMMONIUM-SALTS WITH BUTYLLITHIUM AND WITH LITHIUM HYDRIDE - NEW ROUTES TO FULLY ANHYDROUS INORGANIC LITHIUM COMPLEXES
BARR D, SNAITH R, WRIGHT DS, MULVEY RE, WADE K
J AM CHEM SOC, 1987, 25, 7891-7893.


3 MODEL STRUCTURAL TYPES IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURES OF DIMERIC [PH(ME)NLI.ME2NCH2CH2NME2]2 AND MONOMERIC PH(NAPHTHYL)NLI.MEN(CH2CH2NME2)2 AND OF [PH(NAPHTHYL)NLI.TMEDA]2, A LOOSE DIMER
BARR D, CLEGG W, MULVEY RE, SNAITH R, WRIGHT DS
J CHEM SOC CHEM COMM, 1987, 10, 716-718.


ISOLATION AND SOLUTION STRUCTURES OF (PHCH2NLICH2CH2NME2)N AND OF THE TOTALLY RIGID DILITHIUM COMPOUND, (ORTHO-LIC6H4CH2NLICH2CH2NME2)N - EVIDENCE FOR LI... ORTHO-HC INTERACTIONS
BARR D, SNAITH R, WRIGHT DS, MULVEY RE, JEFFREY K, REED D
J ORGANOMET CHEM, 1987, 01-Feb, C1-C6.